Heterogeneous catalysts for CO<sub>2</sub> hydrogenation to formic acid/formate: from nanoscale to single atom
نویسندگان
چکیده
This review provides an overview of advances on constructing heterogeneous nanostructured and single atom catalysts for CO2 hydrogenation to formic acid/formate. The main focus is placed structure–activity correlations mechanistic insights.
منابع مشابه
Coupling a single trapped atom to a nanoscale optical cavity.
Hybrid quantum devices, in which dissimilar quantum systems are combined in order to attain qualities not available with either system alone, may enable far-reaching control in quantum measurement, sensing, and information processing. A paradigmatic example is trapped ultracold atoms, which offer excellent quantum coherent properties, coupled to nanoscale solid-state systems, which allow for st...
متن کاملSingle-site heterogeneous catalysts.
Intellectually, the advantages that flow from the availability of single-site heterogeneous catalysts (SSHC) are many. They facilitate the determination of the kinetics and mechanism of catalytic turnover-both experimentally and computationally-and make accessible the energetics of various intermediates (including short-lived transition states). These facts in turn offer a rational strategic pr...
متن کاملFrom Pd nanoparticles to single crystals: 1,3-butadiene hydrogenation on well-defined model catalysts.
Although 1,3-butadiene hydrogenation is known to be a structure-sensitive reaction, correlation of the catalytic activity with the exact Pd particle surface structure shows that the reaction is in fact particle size independent.
متن کاملSynthesis of Single Atom Based Heterogeneous Platinum Catalysts: High Selectivity and Activity for Hydrosilylation Reactions
Catalytic hydrosilylation represents a straightforward and atom-efficient methodology for the creation of C-Si bonds. In general, the application of homogeneous platinum complexes prevails in industry and academia. Herein, we describe the first heterogeneous single atom catalysts (SACs), which are conveniently prepared by decorating alumina nanorods with platinum atoms. The resulting stable mat...
متن کاملConverting homogeneous to heterogeneous catalysts
Homogeneous transition metal complex catalysts for organic industrial processes are converted to catalysts which are heterogeneous with respect to the reactants, and which have substantially equal catalytic activity to the homogeneous catalysts. This is done by reacting a normally homogeneous transition metal complex catalyst with a metal bridging ligand which substantially duplicates the ligan...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Energy and Environmental Science
سال: 2021
ISSN: ['1754-5706', '1754-5692']
DOI: https://doi.org/10.1039/d0ee03575k